What is Gibbs Free Energy?

Gibbs free energy-chemistry?

  • Answer:

    Well, the use of the word "free" in this case really means "available". Gibbs free energy was in fact originally called available energy. The concept was developed in the 1870s by the American mathematician Josiah Willard Gibbs. In 1873, Gibbs described this “available energy” as the greatest amount of mechanical work which can be obtained from a given quantity of a certain substance in a given initial state, without increasing its total volume or allowing heat to pass to or from external bodies, except such as at the close of the processes are left in their initial condition.

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Well, the use of the word "free" in this case really means "available". Gibbs free energy was in fact originally called available energy. The concept was developed in the 1870s by the American mathematician Josiah Willard Gibbs. In 1873, Gibbs described this “available energy” as the greatest amount of mechanical work which can be obtained from a given quantity of a certain substance in a given initial state, without increasing its total volume or allowing heat to pass to or from external bodies, except such as at the close of the processes are left in their initial condition.

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