Is there a picture of how the atomic orbitals overlapped in CO2?
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Answer:
Yes. First you have to understand the hybridization of the carbons and the oxygens. The carbon only needs two sigma bonds and therefore only needs to hybridize two atomic orbitals: sp. The oxygen needs three hybrid orbitals, one for the sigma bond to carbon and two to hold the two unshared electron pairs. Oxygen is therefore sp^2 hybridized: Now that leaves carbon with two p orbitals and oxygen with one p orbital. the p orbitals overlap to form pi-bonds: Notice that the pi-bonds are rotated 90 degrees to each other. Credit where it is due: I could have drawn these pictures, eventually, and with minimal success, If I was determined and had over-estimated my ability to draw, but I found them here: http://chemistry.tutorvista.com/inorganic-chemistry/co2-molecular-geometry.html Cheers!
Andrew Wolff at Quora Visit the source
Other answers
Here it is: Diagram is wrong - thanks to Andrew for pointing it out. Px orbitals on O should be sp^2 hybrids.
Michael Flynn
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